Pre-stressed curved ceramic plates/tiles and method of producing same

ABSTRACT

A pre-stressed curved plate comprising a curved plate having at least one concave surface, the curved plate being enveloped and adhesively bonded with tensioned reinforcing fibers, whereby the reinforcing fibers are first wound around the plate under tension being spaced apart from the concave surface and subsequently subjected to pressure to stretch and bond the reinforcing fibers to the surfaces of the plate, where upon bonding, the tensile strain of the fiber introduces stress in the plate.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a U.S. National Phase Application under 35 U.S.C.371 of International Application No. PCT/IL2015/050107 filed on Jan. 29,2015 and published as WO 2015/114632 A1 on Aug. 6, 2015, which claimspriority to Isreal Patent Application No. 230775 filed on Feb. 2, 2014.The entire disclosures of all of the above applications are incorporatedherein by reference.

FIELD OF THE INVENTION

The present invention relates to pre-stressed curved ceramic plates thathave improved ballistic protection characteristics and improvedsurvivability under static and dynamic loading. The invention describesthe structure of the plate, pre-stressed by an external envelope ofstretched fibers bonded to the plate, and method of producing them.

BACKGROUND OF THE INVENTION

Ceramic materials are widely used for ballistic protection with thepurpose of overcoming the high power penetration of projectiles, such asarmor piercing (AP) projectiles, due to their relatively low density,high rigidity and high compression strength. See C. Barry Carter, M.Grant Norton, Ceramic Materials Science and Engineering, SpingerScience, 2007. Usually, ceramics are used in structures for ballisticprotection in the form of plates, tiles, pellets or specially shapeceramic elements.

The significant disadvantage of these ceramic components is their lowfracture toughness and the formation of a wide net of relatively longcracks during fracture. Such behavior of ceramic components reducestheir ability to protect against not only around the local impact zone,but also around the wide area, which is affected by propagated cracks.

The impact on the ceramic component by a projectile generates thepropagation of compression stress waves, which are reflected back fromthe free surfaces of the protection plate as tensile waves.

The ceramic materials have low tensile strength and usually thesetensile stresses lead to the fracture of the ceramic component. It istherefore reasonable to assume that pre-stressing (initial compression)the ceramic component in a ballistic protection structure, shoulddecrease the level of reflected tensile stresses after impact, andimprove the protective ability of the ceramics component in a protectionstructure.

D. Sherman, J. PHYS IV FRANCE 7 1997, showed that inducing thecompression stresses in the ceramics by confined frame reducessignificantly their damage from impact.

T. J. Holmquist, International Journal of Impact Engineering, November2003, evaluated the response of ceramic targets with and withoutpre-stress subjected to projectile impact. The results demonstrate thatballistic performance of confined ceramic targets can be improved bypre-stressing the ceramic.

U.S. Pat. No. 6,389,594 describes that an applying of the high isostaticpressure on a monolith ceramics wrapped by a composite materialsimpregnated with adhesives to cure it, induces the internal stressesinto the ceramics and improves the multi hit capabilities of the armor.

U.S. Pa. No. 6,601,497 discloses an armor component that includes a tilehaving a perimeter, with optional recess to encase a wrapping materialwrapped around the perimeter of the tile. The purpose of wrapping thetile is to prevent lateral expansion of the tile if it is hit. Thewrapping material pre-stresses the tile, however the technique used herelimits the degree of tensioning of the wrapping material by relativelylow ability of tensioners and delivery system for the wrappingmaterials, and does not take an advantage of the tensile ability ofthem. The level of pre-stressing of the tile depends on the perimetergeometry of the tile, where the circular perimeter provides a uniformpressure on the tile recess. The straight sections of the tile perimeterwill not supply any pressure on the tile, so this technology shouldn'tbe effective for monolithic ceramic plates that usually have straightperimeter lines, like personal protection ceramic plates.

U.S. Pat. No. 7,300,893 describes an armor including a strain ratehardening elastomers. An option to wrap the ballistic clothes or fibersaround the ceramic tiles is suggested in this invention as a way toencapsulate the elastomer, and not for pre-stressing of the ceramicplate.

U.S. Pat. No. 7,827,899 describes an armor panel to protect a body froman incoming projectile, comprising the ceramic or glass-ceramic plateand backing polyethylene clothes, encapsulated within by a wrappinglayer and bonded together by applying an external pressure on thiswrapping layer. An armor panel, produced by this way, contains theexternally wrapped layer, but this layer doesn't induce any significantpre-stressing of the internal ceramic plate.

The above prior art relates to pre-stressing anti-ballistic flat ceramicarticles.

It is an object of the present invention is to provide anti-ballisticpre-stressed curved monolithic plates/tiles and a method of producingsame.

It is a further object of this invention to provide a method ofpreparing pre-stressed anti-ballistic curved plates/tiles.

Anti-ballistic articles containing pre-stressed curved plates/tilesaccording to the present invention have superior ballisticcharacteristics including significant reduction of damages to the platewhen hit, thus, providing armor plate with an enhanced multi-hitcapabilities. In addition, anti-ballistic articles containingpre-stressed curved plates of the present invention are of relativelylower weight and decreased thickness than conventional ballisticarticles for achieving the same affect.

Further objectives, features and advantages of the invention will becomeapparent from the following detailed description taken in conjunctionwith the following figures.

SUMMARY OF THE INVENTION

In accordance with the present invention, there is provided apre-stressed curved plate comprising a curved plate having at least oneconcave surface, said curved plate being enveloped and adhesively bondedwith tensioned reinforcing fibers, whereby the reinforcing fibers thatwere wound around the concave side of the plate and spaced apart fromthe concave surface were subjected to pressure at elevated temperatureto stretch and bond the reinforcing fibers to the surfaces of the platesand maintain the tension after cooling, thereby stressing the plate,said bonding being effected by either applying an adhesive to thesurfaces of the curved plate prior to winding the reinforcing fibers orcoating the reinforcing fibers prior to or during winding.

The bonded fibers maintain the internal tension due to their stretchedstatus and induce compression stress in the plate.

It is to be understood that the term plate used herein includes singlecurve or multi-curve plates or tiles and shells containing at least oneconcave zone.

The invention also provides methods for preparing stressed curvedceramic plates, as follows.

a. a curved plate is coated with adhesive.

pre-tensioned reinforcing fibers are wound around the ceramic plate,contacting the convex surface of the plate, and spanning across theconcave surface of the plate, leaving a distance between the fibers andthe convex surface.

external pressure, such as by autoclave or press is then applied,optionally at elevated temperature, to the wound fiber on the concaveside of the plate, to stretch it until it comes in contact with theconcave surface of the plate and is bonded thereto by curing theadhesive.

cooling the plate and releasing the external pressure, whereby thebonded tensioned fibers induce compression stress on the plate.

b. the same procedure as a., with the exception that the reinforcingfibers are pre-impregnated with adhesive prior to winding or areimpregnated during winding.

c. Where the tensile strength of reinforcing fibers is limited and willnot allow the fibers to stretch sufficiently under applied pressure andelevated temperature, to contact the concave surface, one can place aremovable spacer on the concave surface so that the reinforcing fiberswill be wound around the spanner, increasing the length of the fiberloop, so that when the spacer is removed the reinforcing fibers willhave enough length and tenacity be pressed against the concave surfaceand adhere thereto.

DETAILED DESCRIPTION OF THE INVENTION

In accordance with the present invention, the curved plate is preferablya ceramic plate and can be made of aluminum oxide (Al2O3), boron carbide(B4C), silicon carbide (SiC), boron silicon carbide (BSC), titaniumdiboride (Ti B2), aluminum nitride, silicon nitride, sintered siliconcarbide, sintered silicon nitride, and glass-ceramic or combinationsthereof. It is preferred that the plate have a thickness of between 2-30mm. Furthermore, the plate, tile or shell may also be multi-curvedcontaining at least one concave zone.

The reinforcing fibers are selected from aramid,poly(p-phenylene-2,6-benzobisozazole), glass, carbon, thermoplastics(polyamide, polyethylene, polypropylene) or metal (boron, steel,aluminum) fibers.

Suitable adhesives for bonding the fibers to the curved ceramic plateare preferably hot melt thermoplastic adhesives like polyethylene andpolypropylene films or thermosetting adhesives like epoxy withoptionally high or low curing temperatures, rubber or elastomer basedadhesives, ceramic adhesives.

The fibers are preferably impregnated with an adhesive material eitherbefore or during the winding, but before subjecting them to expansion byexternal pressure. Alternatively, the plate can be coated with anadhesive prior to winding the reinforcing fiber.

The pre-stressed curved plate can form an insert for either personalbody armor, or antiballistic panels for vehicles, ships, aircrafts andhelicopters, or for a helmet.

One advantage of the pre-stressed curved plate of the present inventionis that it has increased multi-hit capability.

A second advantage of the pre-stressed curved plate anti-ballisticarticles containing according to the present invention is that theyachieves the same ballistic characteristics with reduced weight.

During the winding procedure the fibers should have some initial tensionand not be slack to assure tight winding. This can be achieved bytensioners, see S. T. Peters, W. D. Humphrey, R. F. Foral, FilamentWinding, Composite Structure, Fabrication, SAMPE, ISBN 0-938994-81-6.

To maintain the tension in the wound reinforcing fibers and to inducethe compression in the plate, the wound plate should be cured underapplied external pressure and optionally at an elevated temperature. Theexternal pressure should be sufficiently high to maintain full contactbetween the fibers and the concave surface of the plate during thecuring of adhesive and final bonding of the stretched fibers to theplate. The degree of compression of the plate will depend on thecurvature of the plate, the direction of winding trajectory of thefibers, and elastic modulus of the fibers. Thus, the same fibers willinduce different compressions in plates with different curvatures.

In cases where the ultimate tensile strain of a fiber is so low thateven under pressure and elevated temperature it would not stretchsufficiently to reach and bond to the concave surface of a ceramicplate, then it is possible to interpose a removable spacer between theconcave surface of the plate and the wound fiber. The removable spacershould have an appropriate geometry to increase the length of the fibersspanning the concave surface of the curved plate, in effect transformingthe concave side to convex with respect of the winding. Thus, whenpressure is applied to the wound plate and the spacer is removed thefibers will be sufficiently stretched to be pressed against the concavesurface of the plate and be bonded thereto. After bonding the tensilestrain of the fibers will induce stress to the plate, which ismaintained upon cooling.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 illustrates a curved ceramic plate before winding withreinforcing fibers.

FIG. 2 is a cross-sectional view of a curved ceramic plate woundinitially with reinforcing fibers in accordance with the presentinvention.

FIG. 3 is a cross-sectional view of a curved ceramic plate with woundfibers stretched and bonded to the surfaces of the plate.

FIG. 4 is a cross-sectional view of a curved ceramic plate with spacerwound initially with reinforcing fibers prior to applying pressure atelevated temperature.

DETAILED DESCRIPTION OF THE DRAWINGS

FIG. 1 is a perspective view of a curved ceramic plate 10 having aconcave surface 12 and a convex surface 14. In FIG. 2 the curved plate20 is wound with adhesive coated reinforcing fibers 16 under tension.Fibers 16 thus come in direct contact with the convex surface 14 andloops around the concave surface 12 forming a taught straight linebetween the edges 17 and 19 of the plate, leaving a space 15 between thetautly wound fibers 16 a and the concave surface 12 of the plate. FIG. 3shows fibers 16,16 a wound around a curved ceramic plate 30 after beingsubjected to elevated temperature of about 180° C., while applyingpressure (see the arrows) against the tensioned wound fibers 16,16 a,pressing the fibers against the surfaces 12, 14 and curing it. Curingcan be done by means of a hydroclave, autoclave, isotactic press orother suitable apparatus as described in U.S. Pat. No. 6,389,594. Thetensioned wound fibers 16,16 a are thus bonded to the concave surface 12and compress the curved plate.

FIG. 4 illustrates in cross-section a curved ceramic plate 40 having aconcave surface 12 and a convex surface 14. A removable spacer 42 isplaced on the concave surface 12. Reinforcing fibers 44, 44 a having lowtensile strain, which would prevent the fibers from being pressedagainst the concave surface 12 under pressure were they stretched tautacross line x-x, are wrapped around a spacer 42 raising fibers 44 a overthe concave surface 12 above the line x-x. This increases the length offibers 44 a on the concave side sufficiently so that when thetemperature is raised and pressure is applied, and the spacer 42 isremoved, fibers 44 a will stretch sufficiently to reach the concavesurface 12 to be bonded to the plate and cured.

The type of fiber should be chosen according to its possible elongationand maximum elastic modulus to increase the compression stresses in theplate.

It should be noted that by using different fibers and/or differentadhesives and/or other bonding conditions such as different processingtemperature or pressure, one may vary the degree of impregnation and/orthe degree of tensioning of the fibers and/or the degree of compression,which may affect the degree of stress in the ceramic plate/tile.

In practice, ceramic plates of this invention are generally backed withan anti-ballistic cloth in anti-ballistic body protecting articles.

EXAMPLE

A number of ceramic body armor articles were prepared as follows.Aluminum oxide double curved ceramic plates 7.1 mm thick and weighing anaverage of 2100 g were wound with 200 g of T700 carbon fibers undertension, treated under pressure and 180 degrees temperature topre-stress the plates, and backed with 23 layers of polyethylene cloth,with average weight of 460 g including adhesive. These articles had ageneral weight of 2760 g.

These articles were tested against APM2 projectiles with velocity range868-883 m/s and provided good protection (two bullets were stopped bythese articles) whereas articles with the same ceramic plates withoutpre-stressing have to include at least 40 layers of polyethylene clothwith average weight of 2900 g to provide the same ballistic protection.

1. A pre-stressed curved plate comprising a curved ceramic plate havingat least one concave surface, said curved ceramic plate being envelopedand adhesively bonded with tensioned reinforcing fibers, wherein thereinforcing fibers are first wound around the ceramic plate undertension and being spaced apart from the concave surface and subsequentlysubjected to pressure to stretch and bond the reinforcing fibers to thesurfaces of the ceramic plate, where upon bonding, the tensile strain ofthe fibers introduces stress in the ceramic plate.
 2. The curved platein accordance with claim 1, wherein the ceramic plate is subjected topressure at elevated temperature.
 3. The curved plate in accordance withclaim 1, wherein said bonding is effected by either applying adhesive tothe surfaces of the curved ceramic plate prior to winding thereinforcing fibers and/-or coating the reinforcing fibers prior towinding.
 4. The curved plate in accordance with claim 1, wherein theceramic plate is a ceramic plate tile.
 5. The curved plate in accordancewith claim 4, wherein the ceramic plate is made of aluminum oxide(Al2O3), hot pressed, sintered or reaction bonded boron carbide (B4C),silicon carbide (SiC), boron silicon carbide (BSC), titanium diboride(Ti B2), aluminum nitride, silicon nitride, sintered silicon carbide,sintered silicon nitride, and glass-ceramic or combinations thereof. 6.The curved plate in accordance with claim 1, wherein the ceramic platehas a thickness of between 3-30 mm.
 7. The curved plate in accordancewith claim 1, wherein the reinforcing fibers are selected from aramid,poly(p-phenylene-2,6-benzobisoxazole), S or E glass, carbon,thermoplastics (polyamide, HMWPE, polyethylene, polypropylene) or metal(boron, steel, aluminum) fibers or their combination.
 8. The curvedplate in accordance with claim 1, wherein the adhesive is selected fromepoxy, phenolic, thermoplastic, thermosetting adhesives, rubber orelastomer based adhesives and ceramic adhesives.
 9. (canceled)
 10. Thecurved plate in accordance with claim 1, further comprising a removablespacer interposed between the concave surface of the ceramic plate andthe reinforcing fibers.
 11. The curved plate in accordance with claim10, wherein the spacer is at least partially melted during theapplication of pressure at elevated temperature.
 12. (canceled)
 13. Amethod of preparing a pre-stressed curved plate having at least oneconcave surface, comprising: winding tensioned reinforcing fibers arounda curved ceramic plate whereby a space is left between the concavesurface of the ceramic plate and the wound reinforcing fibers; applyingexternal pressure to the tensioned fibers to stretch the fibers untilthey contact and bond to the concave surface, and cooling the plate andremoving the external pressure after bonding.
 14. The method of claim13, further comprising heating the tensioned fibers to an elevatedtemperature during the step of applying external pressure to thetensioned fibers, in order to stretch the fibers until they contact andbond to the concave surface.
 15. The method of claim 13, furthercomprising interposing a removable spacer between the concave surfaceand the reinforcing fibers in order to distance the fibers from theconcave surface and to increase their length prior to subjecting thefiber wound ceramic plate to pressure and temperature.
 16. The method ofclaim 15, further comprising ensuring that the removable spacer at leastpartially melts during the application of external pressure at elevatedtemperature.